1,4-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene
نویسندگان
چکیده
The title compound, C(32)H(28)N(2), is a chiral bis-imine in which both imine groups display the common E configuration. The naphthyl groups present different orientations with respect to the central core, as reflected in the dihedral angles of 21.4 (2) and 78.83 (14)° between the benzene and naphthyl mean planes, thus the highest possible C(2) local molecular symmetry is not attained. This C(1) mol-ecular conformation allows multiple C-H⋯π inter-molecular contacts involving all aromatic rings, while no π-π inter-actions are available for the stabilization of the crystal structure. The resulting packing structure is based on mol-ecules stacked along [100].
منابع مشابه
1,3-Bis{(+)-(S)-[1-(1-naphthyl)ethyl]iminomethyl}benzene dichloromethane solvate
In the title compound, C(32)H(28)N(2)·CH(2)Cl(2), the complete Schiff base and solvent molecules are both generated by crystallographic twofold axes, with the two C atoms of the former and the C atom of the latter lying on the rotation axis. The central benzene ring is substituted with two chiral groups including imine functionalities, with the common E configuration. The dihedral angle between...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009